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Direct observation of stretched-exponential relaxation in low-temperature Lennard-Jones systems using the cage correlation function
Eran Rabani, J. Daniel Gezelter, and B. J. Berne
Department of Chemistry,
Columbia University,
3000 Broadway,
New York, New York 10027
We report on the direct observation of stretched exponential
relaxation in low-temperature monatomic Lennard-Jones systems which
were cooled slowly from the liquid phase to form crystals with a large
number of defects. We use the cage correlation function
[E. Rabani, J. D. Gezelter, and B. J. Berne,
J. Chem. Phys. 107, 6867 (1997)] which measures changes in
atomic surroundings to observe the stretched exponential
relaxations. We obtain a distribution of hopping rates assuming that
the origin of the Kohlrausch-Williams-Watts law is from static
disorder in the distribution of barrier heights
PACS numbers: 66.30.-h, 02.70.Ns, 31.15.Qg, 61.43.Er
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