4. Cleanup of an Aqueous Waste Stream

a. Supercritical Water Oxidation to Cleanup an Aqueous Waste Stream Contaminated with Phenol

This project looks at alternatives for the treatment of an aqueous waste stream contaminated with small amounts of phenol, whose concentration must be reduced before the water can be discharged. The process uses supercritical water oxidation to completely destroy the organics in the waste stream. This technology is currently in use for treatment of a mixed aqueous waste by Huntsman Chemical in Austin, TX. The process involves heating the aqueous waste stream to supercritical conditions (> 221 atm and 374°C), where it is mixed with air, which is totally miscible at those conditions. The reaction takes place in a plug flow reactor and the stream is cooled back to ambient conditions.

This process would be an interesting one-semester design project. Material available on this project includes a project report, PFDs and an economic evaluation. Instructors can contact Professor Stadtherr for this information.

CLICK HERE to obtain an Adobe Acrobat file about this project.

Joseph A. Shaeiwitz
Department of Chemical Engineering
West Virginia University
P.O. Box 6102 
Morgantown, WV 26506-6102 
Phone: 304-293-2111 ext.2410
Fax: 304-293-4139
email: shaeiwit@cemr.wvu.edu

Mark A. Stadtherr
Department of Chemical Engineering
University of Notre Dame
Notre Dame, IN 46556
phone (219) 631-9318
FAX (219) 631-8366
email: markst@nd.edu
 
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