Peter C. Burns Massman Professor

Director, Energy Frontier Research Center

Concurrent Professor,

Chemistry and Biochemistry

Biography Ph.D. (Geology) (1994) University of Manitoba

Ph.D. Thesis: The Stereochemistry of Cu2+ Oxysalt Minerals: An Ab Initio Molecular-Orbital Approach

M.Sc. (Geology) (1990) University of Western Ontario

M.Sc. Thesis: Tetrahedral-Site Ordering in Synthetic Gallium Albite

B.Sc. (Honours) (1988) University of New Brunswick

B.Sc. Thesis: Hexaborates From the Cassidy Lake Formation, Sussex, New Brunswick

Research Interests Peter C. Burns has focused most of his research over the past decade on the solid-state chemistry, mineralogy, and environmental chemistry of uranium, as well as the transuranic elements neptunium and plutonium.

In 2005 the Burns research group published the first of a family of novel uranyl peroxide hydroxide spherical nanoclusters. To date, we have reported the synthesis and structures of nanoclusters containing 24, 28, 32, 40 and 50 uranium atoms. Additional papers will be forthcoming that report U16, U20 (multiple topologies), U24 (open), U36, U44 and U60. We will also be completing a "roadmap" for the synthesis of specific members of this complex family of actinide nano-scale clusters.

The Burns group has published extensively in uranium mineralogy, and has reported the crystal structures of dozens of uranyl minerals including autunite, bijvoetite, vandendriesscheite, wolsendorfite, boltwoodite, compreignacite, masuyite, haweeite, weeksite, fontanite, billietite, richetite, zippeite, and studtite.

The structure of studtite, reported by Burns and Kubatko (2003) is the first structure of a peroxide mineral, and the only one published to date. As reported by Kubatko et al. (2003) in Science, studtite forms in nature where radioactivity causes the formation of peroxide in water. Studtite was the first structure found that involved shared edges between any uranyl peroxide polyhedra, and the Burns group later developed a complex group of nano-structured uranium materials based upon this linkage.

The Burns group has examined the impacts of uranium mineralogy on the release of radionuclides from nuclear waste in a geological repository, such as Yucca Mountain. Much of the emphasis has been on neptunium, as it has a long half-life and is potentially mobile in the environment.

Burns has published extensively on borate mineralogy, copper minerals, and a variety of exotic new minerals. He has published structural hierarchies for borate minerals, sulfate minerals, inorganic uranium compounds, and inorganic neptunium compounds.
Professional Experience
2009-present Director, Energy Frontier Research Center
2009-present The Henry Massman Professor of Civil Engineering & Geological Sciences, University of Notre Dame
2002-2009 Massman Chair of the Department of Civil Engineering and Geological Sciences, University of Notre Dame
2007-present Concurrent Professor of Chemistry and Biochemistry, University of Notre Dame
2002-2009 Professor of Civil Engineering and Geological Sciences, University of Notre Dame
2002-present Special Term Appointment, Chemistry Division, Argonne National Laboratory
2000-2002 Massman Associate Professor of Civil Engineering and Geological Sciences, Department of Civil Engineering and Geological Sciences, University of Notre Dame
1999-2002 Director of Graduate Studies, Department of Civil Engineering and Geological Sciences, University of Notre Dame
1999-2002 Associate Professor of Civil Engineering and Geological Sciences, University of Notre Dame
1997-1999 Assistant Professor of Civil Engineering and Geological Sciences, University of Notre Dame
1996-1997 Visiting Assistant Professor, Department of Geology, University of Illinois in Urbana-Champaign
1995-1996 NSERC Post-Doctoral Fellow, Department of Earth and Planetary Sciences, University of New Mexico
Topic: Structural hierarchy of U6+ phases: applications to the disposal of nuclear Waste
1994-1995 NSERC Post-Doctoral Fellow, Department of Earth Sciences, University of Cambridge
Topic: Phase transitions and microstructures of minerals
1994-1995 Research Fellow, Clare Hall College, University of Cambridge
1990-1994 Lecturer and Teaching Assistant, Department of Geological Sciences, University of Manitoba
1988-1989 Teaching Assistant, Department of Geology, University of Western Ontario
1986-1988 Teaching Assistant, Department of Geology, University of New Brunswick
1986 Research Assistant, Department of Geology, University of New Brunswick
COMMITTEES TO RENDER SCIENTIFIC JUDGEMENT
2009-2010 National Academy of Science Nuclear Waste Form Committee
2010-2011 Chair, Officer Nomination Committee, Mineralogical Society of America
2008-2009 Chair, Roebling Medal Committee, Mineralogical Society of America
2010-2012 Past-President, Mineralogical Association of Canada
2008-2010 President, Mineralogical Association of Canada
2006-2008 Vice President, Mineralogical Association of Canada
2008-2010 Member of Council, Mineralogical Society of America
2005-present College of Reviewers for the Canada Research Chairs program
2005-2008 Advanced Photon Source General Proposal Review Panel
2005-2006 Editorial Advisory Board, Elements, An International Magazine of Mineralogy, Geochemistry and Petrology
2001-2006 Associate Editor, American Mineralogist
1998-2004 Associate Editor, Canadian Mineralogist
1998-2006 Member of Council, Mineralogical Association of Canada
1999-2000 Lecture Program Committee, Mineralogical Society of America
2001 Chair, Lecture Program Committee, Mineralogical Society of America
2007-2008 Chair, Crystallography Award Committee, Mineralogical Society of America
2001-present Public Service Committee, Mineralogical Society of America
1999 Editor, Mineralogical Society of America Reviews in Mineralogy "Uranium: Mineralogy, Geochemistry and the Environment"
HONORS/AWARDS
2007 Thompson ISI top ten most highly cited geoscientists 1996-2007.
Biographies in Who's Who in Science and Engineering, Who's Who in America, Who's Who in the Midwest, Who's Who Among America's Teachers, Who's Who in the World, etc.
2003 Mineral burn site named by a group of Russian and Canadian scientists
2001 MSA Award and Life Fellow of the Mineralogical Society of America
1999 Donath Medal of the Geological Society of America
1998 Young Scientist Medal of the Mineralogical Association of Canada
1997 Hawley Medal (best paper award) of the Mineralogical Association of Canada
1995 Elected Life Member of Clare Hall College, University of Cambridge
1994 Winthrop Spencer Gold Medal for Outstanding Achievement in Geological Sciences
1994 Natural Sciences and Engineering Research Council of Canada Post Doctoral Fellowship
1994 International Centre for Diffraction Data Crystallography Scholarship 1994
1994 Mineralogical Society of America Biennial Grant for Research in Crystallography
1994 Elected Research Fellow of Clare Hall, University of Cambridge
1993 International Centre for Diffraction Data Crystallography Scholarship 1993
1992 The J.L. Lightcap Award for Highest Standing in U. of M. Ph.D. Program
1992 University of Manitoba Graduate Fellowship
1988-92 Natural Sciences and Engineering Research Council of Canada Graduate Scholarship.
1991 Dr. George Brownell Memorial Prize for Highest Standing in Geological Sciences
1991 Geological Association Graduate Seminar Prize
1991 Sigma Xi Student Award for Excellence in Research
1988 U. W. O. Special Entrance Scholarship
1987 Canadian Institute of Mining and Metallurgy Earth Science Scholarship
1987 Tom and Parker Hickey Memorial Scholarship
1987 Natural Sciences and Engineering Research Council of Canada Student Research Assist.
1987 The Wood Scholarship
1986 Fredericton MAC-GAC 1985 Scholarship
1986 U. N. B. Alumni Undergraduate Scholarship
1986 Natural Sciences and Engineering Research Council of Canada Student Research Assist.
1986 Tom and Parker Hickey Memorial Scholarship
Recent Papers

Sigmon, G.E., Ling, J., Unruh, D.K., Moore-Shay, L., Ward, M., Weaver, B. & Burns, P.C.: Uranyl-peroxide interactions favor nano-cluster self-assembly. Journal of the American Chemical Society 131, 16648-16649.

Sigmon, G.E., Weaver, B., Kubatko, K.A. & Burns, P.C. (2009): Crown and bowl-shaped clusters of uranyl polyhedra. Inorganic Chemistry 48, 10907-10909.

Gorman-Lewis, D., Shvareva, T., Kubatko, K.A., Burns, P.C., Wellman, D.M., McNamara, B., Szymanowski, J.E.S., Navrotsky, A. & Fein, J.B. (2009): Thermodynamic properties of autunite, uranyl hydrogen phosphate, and uranyl orthophosphate from solubility and calorimetric measurements. Environmental Science and Technology 43, 7416-7422.

Sigmon, G., Unruh, D.K., Ling, J., Weaver, B., Ward, M., Pressprich, L., Simonetti, A. & Burns, P.C. (2009): Symmetry vs. minimal pentagonal adjacencies in uranium-based polyoxometalate fullerene topologies. Angewandte Chemie International Edition 48, 2737-2740. Highlighted in Nature March 20, 2009.

Unruh, D., Burtner, A. & Burns, P.C. (2009): Monodentate peroxide coordination in trimers of U6+ polyhedra. Inorganic Chemistry 48, 2346-2348.

Schindler, M., Freund, M., Hawthorne, F.C., Burns, P.C. and Maurice, P.A. (2009): Dissolution of uranophane: An AFM, XPS, SEM and ICP study. Ge ochimica et Cosmochimica Acta 73, 2510-2533.

Schindler, M., Hawthorne, F.C., Freund, M.S. and Burns, P.C. (2009): XPS spectra of uranyl-minerals and synthetic uranyl compounds II. The O 1s spectrum. Geochimica et Cosmochimica Acta 73, 2488-2509.

Schindler, M., Hawthorne, F.C., Freund, M.S. & Burns, P.C. (2009): XPS spectra of uranyl minerals and synthetic uranyl compounds I. The U 4f spectrum. Geochimica et Cosmochimica Acta 73, 2471-2487.

Image Gallery Please visit www.petercburns.com for images and information.
Contact Information Phone: 574-631-7852
Fax: 574-631-9236
Email: pburns(at)nd.edu
Primary Research Areas Actinide chemistry, solid state chemistry, mineralogy, crystallography, environmental mineralogy
Lab Personnel Ginger Sigmon

Daniel Unruh
Jessica Beard
Amanda Albrecht
Christine Wallace
Miller Wylie
Enrica Balboni
Kristi Pellegrini

Jie Ling

Christian Lipp
Zuolei Liao
Laurent Jouffret
Jie Qiu

Courses Mineralogy
Mineral Optics
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Department of Civil Engineering and Geological Sciences.      156 Fitzpatrick Hall, Notre Dame, IN 46556-5637      Phone: 574-631-5380     Fax: 574-631-9236